BALANCING REDUCTION AND OXIDATION REDOX EQUATIONS When balancing redox reactions as written below. MnO4- + Cl- ==> MnO2 + Cl2 We begin by checking for the oxidation number value changes of one of the elements for this case, manganese on both sides of the equation. Calculating the oxidation number on both sides , it will be clearly seen that manganese changes from +7 to +4 meaning that it's trending towards the negatives. This implies that there is gain of electrons. The oxidation number is seen to decrease. In the case of the chloride ion there is a change from -1 to 0 indicating an increase in oxidation number hence the addition of electrons. In summary,manganese gains electrons thereby undergoing reduction while chloride ion losses electron to manganese to become chlorine gas. Writing a balanced redox equation, requires the following Divide the equation break the whole equation into two half equations for each species and ...